organotins definition

Organotins - Background document for the development of the GDWQ (December 2020) The most toxic forms have three tin-carbon bonds and have been widely used as biocides and pesticides. These compounds are classified by the number of organic functional groups bond to tin i.e. Independent tests showed that organotins are present in a wide range of textile articles, 10 REACH Definition: Persistent, Bio-accumulative and Toxic (PBT): Annex XIII defines criteria for the identification of substances that are Persistent, Bio-accumulative and Toxic (PBTs) and Annex I lays down general provisions for PBT assessment. organotin adj of, concerned with, or being an organic compound with one or more tin atoms in its molecules: used as a pesticide, hitherto considered to decompose safely, now found to be toxic in the food chain Uses in the Supply Chain Organotins are often used as a heat stabilizer in polyvinyl organotins. They are organometallic compounds that are used in the preparation of polyvinylchloride (PVC) plastics. The extracted organotin compounds must then undergo derivatization to a volatile form . Organotin compounds (OTs) are synthetic persistent organometallic xenobiotics widely used in several commercial applications. Human exposure results from contaminated seafood, agricultural products and drinking water. This method has been validated and is available for use but has not yet been formally in incorporated into the SW-846 Compendium. In other words, the suspended ceiling does not make up a permanent structural foundation, but rather serves as a covering for the more solid framework above. In rodents, organotin exposure induces developmental and reproductive toxicity as well as alteration of metabolic homeostasis through its action as an obesogen. Organotins have many applications, such as coatings, anti-odour/anti-fungal additives, pesticides, biocides in marine antifoulant paints, catalysts, wood treatments and preservatives. Present concerns about exposure to organotins arises from their . They exert well-described harmful effects in brain, liver, adipose tissue, and reproductive organs, as they are endocrine-disrupting chemicals (EDCs), but the effects in the kidneys are less known. . Organotin compounds have varying degrees of toxicological properties, depending on the nature and number of alkyl groups bonded to the tin atom. Organotin compounds or stannanes are chemical compounds based on tin with hydrocarbon substituents. A sensitive, confirmatory ultra-high performance liquid chromatography-tandem mass spectrometry based on modified QuEChERS was developed and validated to detect five organotin compounds in classical tropical fruits and meets the routine monitoring requirements for trace organotins in tropical fruits. PVC contains dangerous chemical additives including phthalates, lead, cadmium, and/or organotins, which can be toxic to your child's health. noun. Chemical compounds used in anti-foulant paints to protect the hulls of boats and ships, buoys, and pilings from marine organisms such as barnacles. Organotin Definition & Meaning | Dictionary.com organotin / ( ntn) / Save This Word! Human exposure and health-effect data are relatively rare for organotins, but studies have documented the presence of these compounds in human blood,19 milk,20 and liver21 samples. We found 4 dictionaries with English definitions that include the word organotins: Click on the first link on a line below to go directly to a page where "organotins" is defined. Environment Dictionaries. used on the hulls of ships and marine apparatus. Organotins or organotins, definition: Organotins are chemical compounds derived from tin, also known as organotins. Organotin chemistry is part of the wider field of organometallic chemistry. Grammatically, this word "organotins" is a noun, more specifically, a noun form. As the world of organotin chemicals is quite extensive . Organotin compounds (organotins) are substances composed of tin directly bound to different organic groups. organotin (pl. organotins Organozinnverbindungen For the report, WWF tested 27 different foodstuffs from countries around Europe for eight different groups of man-made chemicals - organochlorine pesticides, PCBs, brominated flame retardants, perfluorinated chemicals, phthalates, organotins , alkylphenols and artificial musks. First, the organotin compounds must be extracted from the sample using organic solvents. organism: [noun] a complex structure of interdependent and subordinate elements whose relations and properties are largely determined by their function in the whole. click . Organotin compounds are those with tin linked to hydrocarbons. Organotin Compounds Organotin compounds represent one of the most studied classes of chemicals that are proposed to be obesogenic. It helps in wood treatment and preservation. organotins. Human exposure results from contaminated seafood, agricultural products and drinking water. Then it analyzed the world's main region market conditions, including the product price, profit, capacity . Definiteness: Level 1 12345678910 organotin (pl. The determination of trace-amount organotins in plastic food packaging materials is of great significance in food safety. The support of Dr Mika Takahashi, Organotins include chemicals like tributyltin (TBT), a wood preservative and marine anti-fouling paint and fungicide, now banned (in part due to their ability to turn female snails into males, but that's another story).Dibutyltin (DBT) is used as a stabilizer in PVC plastic and a metabolite of TBT. What is the abbreviation for Organotins? Highly toxic tributyltin (TBT) has been banned internationally in anti-fouling paints for ship hulls. organotin Any tin-based organic compound in wide use for marine anti-fouling paints, wood catalysts, plasticisers, slimicides, in industrial water systems and as fungicides. Organotin chemicals are those compounds containing at least one bond between tin and carbon. Organotins are a large class of chemicals. Definition of antifouling agent: A substance which prevents or retards fouling or marine underwater growth on plants, rocks, ships' bottoms etc. b The organotins are listed as the chloride salt, however this method is designed to detect the free cation, whether from the chloride salt, oxide, etc., of the organotin. Organotin compounds are widely applied as pesticides; as preservatives of wood, paper, textiles, leather, and glass; in heat/light protection of PVC plastics; and in antifouling paints. cadmium, and/or organotins, which can be toxic to your child's health. There are 4 classes of organotins: Mono-organotin compounds containing one carbon group attached to a tin atom and used primarily as heat stabilizers in polyvinylchloride films organotins) Any compound of this kind. It is the main active ingredient in biocides used to control a wide spectrum of organisms. OTS abbreviation stands for Organotins. Most of the analytical speciation methods applied to actual environmental media have involved prior derivatization to transform organotin compounds into volatile hydrophobic analytes amenable to Organotin chemicals are those compounds containing at least one bond between tin and carbon. !"!#$ %& ' ' 1 of 2 Single Residue Methods organotin Any tin-based organic compound in wide use for marine anti-fouling paints, wood catalysts, plasticisers, slimicides, in industrial water systems and as fungicides. Whether you're already certified organic, considering transitioning all or part of your operation, or working with organic producers, we have resources for you. organotin Any tin-based organic compound in wide use for marine anti-fouling paints, wood catalysts, plasticisers, slimicides, in industrial water systems and as fungicides. (IUPAC) have evaluated speciation and provided a definition as follows . The definition of a fire-resistive or fire-rated cable is a cable that will continue to operate in the presence of a fire. The background document on organotins in drinking-water for the development of the World Health Organization (WHO) Guidelines for drinking-water quality (GDWQ) was prepared by Dr Akihiko Hirose of the National Institute of Health Sciences of Japan. They are synthetic industrial products. Some other pesticide uses continue. Organotin compounds are those containing tin and carbon. On the industrial scale, organotin compounds are usually prepared by alkylation of SnCl4 with organo-magnesium or -aluminum compounds. It belongs to the trialkyl organotin family. About us Organotins Organotins are considered in the WHO Guidelines for Drinking-water Quality (GDWQ). Definition in the dictionary English. These compounds are endocrine-disruptors and cause severe reproductive effects in aquatic organisms. Some of its applications are listed below: 1. A drop ceiling, or suspended ceiling, consists of panels or tiles that hang a few inches below the main structural ceiling. Here, we report a method for the sensitive and simultaneous determination of o It is used in several commercial products of daily use. Organotin Compounds Organotin compounds represent one of the most studied classes of chemicals that are proposed to be obesogenic. Many USDA agencies serve the growing organic sector. Organotins have quickly become a profitable sector of tin. Organotins include a wide variety of molecules containing tin bound covalently to one to four organic moieties. Organotin substances (organotins) are tin compounds having 1,2,3 or 4 organic groups attached and are designated as mono-, di-, tri- or tetra-organotin depending on the number of tin-carbon bonds in the molecule. Perfluorooctanoic acid (PFOA) is a surfactant used for reduction of friction, and it is also used in nonstick cookware. organotins) Any compound of this kind. It is a valuable source of guidance and direction for companies and individuals interested in Organotins industry. This is commonly known as a circuit integrity (CI) cable and is 2-hour fire-rated. Effect of Trimethyltin Chloride on Slow Vacuolar (SV) Channels in Vacuoles from Red Beet ( Beta vulgaris L.) Taproots: "Although their soil concentrations are low and do not usually exceed the micromolar range, organotins accumulate in plant tissues and trigger numerous changes in their . The high usage of organotins in both plastics and agricultural maintenance as well as the high affinity of the chemicals further confirms this conclusion. Definition of organotinsin English Dictionary NounBForganotinPREorgano- pluralof organotin. Organotin compounds are chemical compounds based on tin with hydrocarbon substituent's. Over the years, a variety of uses has been found for organic and inorganic tin compounds, as fungicides, as stabilisers in plastics, moluscicides, and miticides; they have also been suggested as insect chemosterilants and for other industrial uses. The use of dialkyltin compounds can cause . Definition. They produce endocrine-disrupting effects in mollusks, such as imposex. The report provides a basic overview of Organotins industry including: definition, applications and manufacturing technology. The organotins can be classified into two groups based on their use. Organotin compounds present in environment are mostly polar and involatile, and extracted ionic or complexed organotins need to be derivatized into volatile species for GC analysis. Organotin (IV) compounds have high Lewis acidity and easily expand their coordination numbers to accommodate multidentate anions, such as phosphate and pyrophosphate (PPi), to afford penta- or hexa-coordinated hypervalent structures. This document outlines the proposed risk management actions for these substances, including the choice of risk management instruments. Organotins are synthetic organometallic compounds that are used primarily as pesticides and stabilizers for polyvinyl chloride (PVC) plastic products (CCME 1999). The European Food Safety Authority (EFSA) has issued an opinion on the health risks to consumers associated with exposure to organotins in foodstuffs (EFSA opinion). Commonly found in: Plastics, . The report provides key statistics on market. The sectors that use them most often make use of their biocidal characteristics. 4. 3. It is used as an antifouling agent in ship bottom paints. Organotins find uses in the applications such as biocides preservative for cotton and polyester textiles, as biocides for the protection against odour in sports textile, stabilizer or catalyst in PVC, polyurethane and polyester foams. What does OTS stand for? General (2 matching dictionaries) organotins: Wiktionary [home, info] Organotins: Wikipedia, the Free Encyclopedia [home, info] Tech (2 matching dictionaries) Polycarbonates ( PC) are a group of thermoplastic polymers containing carbonate groups in their chemical structures. organotins in a sentence - Use organotins in a sentence and its meaning 1. They are organometallic compounds that are used in the preparation of polyvinylchloride (PVC) plastics. Human exposure results from contaminated seafood, agricultural products and drinking water. Organotin compounds, or stannanes, are chemical compounds based on tin element bonded to carbon. A sensitive, confirmatory ultra-high performance liquid chromatography-tandem mass . Analysis of organotin compounds usually consists of four steps: (1) extraction; (2) formation of volatile derivative; (3) separation; and (4) detection and quantification. In addition, organotins such as trimethyltin ( TMT ) triethyltin ( TET ), and tributyltin ( TBT ) compounds can exert their effects through similar pathways. What are they? The majority of organotin uses are comprised of five major commercial applications: PVC Heat Stabilizers, Biocides, Catalysts, Agrichemicals, and Glass Coatings. However, due to the complexity of organotins and sample treatment processes, it is still a challenging task. extract organotins from sediment, offering the advantages of the reduction in handling steps and the elimination of the use of hazardous organic solvents. They are easily worked, molded, and thermoformed. Human exposure results from contaminated seafood, agricultural products and drinking water. . 2. Organotins Definition from Society & Culture Dictionaries & Glossaries. EPA Terms of Environment. Commonly found in: Plastics, . Polycarbonate. Definition of antifouling agent: A substance which prevents or retards fouling or marine underwater growth on plants, rocks, ships' bottoms etc. The following document discusses the method that covers the use of solid-phase extraction (SPE) discs, solvent extractions, and micro-liquid chromatography coupled with electrospray ion trap mass spectrometry (ES-ITMS). The kidneys are especially vulnerable to environmental contaminants . organotin Any tin-based organic compound in wide use for marine anti-fouling paints, wood catalysts, plasticisers, slimicides, in industrial water systems and as fungicides. Grignard reagents, RMgX, are prepared from the metal and an alkyl or aryl halide and need large volumes of solvent and are expensive. There was a 60-day public comment period associated with this document. Extensive use in antifouling paints on watercraft (Figure 1) led to the widespread distribution of TBT in water, sediment and biota. 1.2 Additionally, this method may be applicable to other non-volatile, water-soluble, polar, compounds that are amenable to extraction by SPE and are ionizable by LC-ES-ITMS. oj4. 2. Organotin compounds have been used as heat stabilizers in PVC, biocides, wood preservatives, and marine anti-fouling agents. The report firstly introduced the Organotins basics: definitions, classifications, applications and industry chain overview; industry policies and plans; product specifications; manufacturing processes; cost structures and so on. Organotins are pollutants that are used as biocides in antifouling paints. OTs h The endocrine-disrupting chemicals (EDC) present various classes of pollutants with potential neurotoxic actions, such as organotins (OTs). These toxic additives can leach out or evaporate into the air . Organotins are also being used in the manufacture of PVC plastics and have been identified in drinking water and food supplies. The organotins can be classified into two groups based on their use. Some of these highly versatile compounds find uses in manufacture of plastics as stabilizers and catalysts; others are used as agricultural and marine pesticides. What are organotin compounds used for? Key points of Organotins Market Report. Part-of-Speech Hierarchy Nouns Noun forms Noun plural forms Source: Wiktionary Meaning of organotinsfor the defined word. adjective of, concerned with, or being an organic compound with one or more tin atoms in its molecules: used as a pesticide, hitherto considered to decompose safely, now found to be toxic in the food chain QUIZ SHALL WE PLAY A "SHALL" VS. A proposed Risk Management Approach Document for Non-Pesticidal Organotin Compounds was also released in August 2009. There are 4 classes of organotins with tri-substituted organotin compounds having the most toxic effects on the environment. Although phased out as a biocide and marine antifouling agent, TBT is still used as a wood preservative and, along with dibutyltin, as a stabilizer in polyvinyl . The organotins are designated as mono-, di-, tri-, or tetra-organotin compounds and have the general formula (n-C 4H 9), Sn-X, where X is an anion or a group linked covalently through a . The organotins can be classified into two groups based on their use. Where are organotin compounds found? Effect of Trimethyltin Chloride on Slow Vacuolar (SV) Channels in Vacuoles from Red Beet ( Beta vulgaris L.) Taproots: "Although their soil concentrations are low and do not usually exceed the micromolar range, organotins accumulate in plant tissues and trigger numerous changes in their . The inhibitory effect of 12 organotins in a four concentrations (0.001, 0.01, 0.1, and 1.0 mg/liter) of a 12-day growth and on the respiration rate and chlorophyll a content in 9-day tests were . Human exposure may result from dietary sources (e.g., seafood) or contaminated drinking water . Regulation (EC) No #/# of the European Parliament and of the Council of # April # on the prohibition of organotin compounds on ships. tetra-, tri-, di- and mono-organotin compounds. plural of [i]organotin[/i] Examples Stem. . Where are organotin compounds found? Organotins are those compounds containing at least one tin-carbon bond. These toxic additives can leach out or evaporate into the air over time, posing unnecessary dangers to children. They are found in industrial wastewater, plastics and in disinfectants against fungal diseases in materials. Organotins are chemicals which can be found in water systems due to their presence in paints as anti-biofouling agents e.g. The complexation events are outputted by combination with appropriate signaling units. Organotins (OTs) are additives widely used as thermal and light stabilizers in polyvinyl chloride (PVC) plastics. PFOA has been detected in the blood of more than 98% of the general US population. Our vision and mission are the attainment by all peoples of the lowest possible burden of water and sanitation-related disease through primary prevention. Polycarbonates used in engineering are strong, tough materials, and some grades are optically transparent. Organotins, important environmental pollutants widely used in agricultural and industrial applications, accumulate in the food chain and induce imposex in several marine species as well as neurotoxic and immunotoxic effects in higher animals. Generally, the mono-, di-, or tri-substituted organotins have the most applications in the apparel and footwear industry. This paper presents a brief overview of some of the major commercial organotin chemicals, their applications and substitutes, as well as the environmental pressures coming to bear on these products. The consequences of exposure to environmental contaminants have shown significant effects on brain function and behavior in different experimental models. Definitions. Because of these properties, polycarbonates find many . The chemicals further confirms this conclusion significance in food safety due to their in! A drop ceiling, or tri-substituted organotins have quickly become a profitable sector of tin directly bound to organic! 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